Syntheses and crystal structures of mixed-ligand copper(II)–imidazole–carboxylate complexes
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چکیده
منابع مشابه
Syntheses and crystal structures of neutral tetrairon complexes with the unique SCPPh2S ligand.
The novel reactions of cluster salts [(μ-RS)Fe(2)(CO)(6)(μ(4)-CS(2))Fe(2)(CO)(6)][Et(3)NH] with Ph(2)PCl, via the insertion of the PPh(2) group into an activated C-S bond, afford the unprecedented tetrairon complexes with the unique SCPPh(2)S ligand which is coordinated to (μ-RS)Fe(2)(CO)(6) and Fe(2)(CO)(6) units in a μ(4)-k(2)C:k(4)S,S' mode (R = Ph, CH(3)O(2)CCH(2)).
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Interactions of [PPh4]2[0s02C14] and [Bu”,Nl[OsNCl~] with LiZL [H2L = 1,2bis(p-toluenesulphonylamido)benzene] gave binuclear osmium(V1) compounds (PPh,),[Osz 04LZ(p-OH)d (1) and OS~N~L&-OH)~ (2), respectively. The structures of both compounds have been determined by X-ray crystallography. The crystal structure of the [OsZ04LZ@0H),12anion contains two trans-0s02(L) units bridged by two OH groups...
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ژورنال
عنوان ژورنال: Journal of Coordination Chemistry
سال: 2018
ISSN: 0095-8972,1029-0389
DOI: 10.1080/00958972.2018.1460471